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原著論文

  • Harnessing dye-induced photothermal confinement in lipid membranes: A Path to NIR-modulated artificial synaptic vesicles
    Sarker, S. R.; Yamazaki, T.; Sou, K.; Takemura, I.; Kurita, Y.; Nomura, K.; Ichimura, M.; Suzuki, T.; Kai, A.; Araki, T.; Hattori, S.; Furuyama, T.; Chang, Y.-T.; Kiya, T.; Arai, S.
    bioRxiv
    DOI: 10.1101/2024.07.20.604262

  • Near-infrared-light-activatable proximity labeling of bead-binding proteins
    Nakane, K.; Hoshino, Y.; Dodo, K.; Tomoshige, S.; Ishikawa, M.; Furuyama, T.*; Sato, S.
    ChemRxiv

    DOI: 10.26434/chemrxiv-2023-443cj

  • Induced of axial chirality in near-infrared-absorbing ball-shaped ruthenium complexes
    Shinokubo, Y.; Arai, R.; Nishimura, T.; Maeda, K.; Maeda, H.; Segi, M.; Furuyama, T.
    *
    J. Photochem. Photobiol. A 2025, 459, 116089.
    DOI: 10.1016/j.photochem.2024.116089

  • Phototriggered generation of ynol ethers and their rearrangement to ketenes
    Mogami, S.; Baba, M.; Furuyama, T.; Kunishima, M.; Mishiro, K.
    J. Org. Chem. 2024
    , 89, 10709-10718.
    DOI: 10.1021/acs.joc.4c00947

  • Red-light-driven bifunctionalization of styrene derivatives
    Kai, U.; Katsurayama, Y.; Nishida, R.; Kameyama, T.; Torimoto, T.; Furuyama, T.
    *
    J. Org. Chem. 2024, 89, 8178-8184.
    DOI: 10.1021/acs.joc.4c00889

  • Dehydro[12]- and [18]annulene-fused ball-shaped ruthenium complex oligomers: Synthesis, aromatic/antiaromatic effect, and symmetry for near-infrared optical properties
    Ishikawa, S.; Maeda, H.; Segi, M.; Furuyama, T.*

    Chem. Eur. J. 2024, 30, e202400407.
    DOI: 10.1002/chem.202400407
    Selected as a Hot Paper

  • Selective formation of Cu active sites with different coordination states on pseudo-spinel CuAl2O4 and their NO reduction catalysis
    Okuda, A.; Furuyama, T.; Sakai, T.; Machida, M.; Yoshida, H.
    ACS Omega 2024, 9, 11950-11957.
    DOI: 10.1021/acsomega.3c09704

  • Phosphorus(V) tetraazaporphyrin with an intense, broad CT band in the near-IR region
    Yoshida, T.; Okada, Y.; Namikawa, T.; Furuyama, T.*; Kamada, K.; Kobayashi, N.
    Org. Lett. 2024, 26, 1931-1935.
    DOI: 10.1021/acs.orglett.4c000298

  • Phototriggered butenolide formation from a cyclobutenedione and an acidic nucleophile
    Mishiro, K.; Sesumi, A.; Fujii, T.; Furuyama, T.; Kunishima, M.
    Org. Lett. 2024, 26, 380-384.
    DOI: 10.1021/acs.orglett.3c04054

  • Photosensitizing metasurface empowered by enhanced magnetic field of toroidal dipole resonance
    Hasebe, H.; Sugimoto, H.; Katsurayama, Y.; Furuyama, T.; Fujii, M.
    Small 2023, 19, 20232519.
    DOI: 10.1002/smll.202302519

  • Synthesis and photophysical properties of subphthalocyanine substituted with tetraphenylethylene moieties
    Furuyama, T.*; Shitanda, S.; Fukumura, T.; Kobayashi, N.
    J. Porphyrins Phthalocyanines
     2023, 27, 1156-1163.
    DOI: 10.1142/S1088424623500591

  • Decreasing the aggregation and ligand redox potential of metallophthalocyanines through branched ether functionalization
    McKearney, D.; Zhou, W.; Scollon, M.; Furuyama, T.*; Williams, V. E.; Leznoff, D. B.
    J. Porphyrins Phthalocyanines 2023, 27, 452-462.
    DOI: 10.1142/S1088424623500141

  • Rational design of functionalized near-infrared absorbing phthalocyanines by three-component coupling strategy
    Iwamoto, T.; Maeda, H.; Segi, M.; Furuyama, T.*
    J. Porphyrins Phthalocyanines 2023, 27, 218-225.
    DOI: 10.1142/S1088424622300063

  • (1,6)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions. Formation of sandwich, dumbbell, and pseudorotaxane complexes
    Maeda, H.; Saito, G.; Furuyama, T.; Segi, M.
    New. J. Chem. 2023, 47, 1388-1400.
    DOI: 10.1039/D2NJ04790J

  • Regioselective rearrangement reactions of naphthyl naphthylmethyl ethers by using Lewis acids or UV light irradiation
    Maeda, H.; Nakamura S.; Furuyama, T.; Segi, M.
    J. Mol. Struct. 2023, 1274, 134450.
    DOI: 10.1016/j.molstruc.2022.134450

  • Synthesis of 3-oxatricyclo[7.2.0.0   ]undeca-7,10-dienes through intramolecular photocycloaddition reactions of alkenes to 1,8 a-position of naphthalene ring
    Maeda, H.; Kubo, Y.; Nakashima, R.; Mizuno, K.; Furuyama, T.; Segi, M.
    Eur. J. Org. Chem. 2022, 45, e202201051.
    DOI: 10.1002/ejoc.202201051

  • Cationic axial ligand effects on sulfur-substituted subphthalocyanines
    Ogura, Y.; Nakano, M.; Maeda, H.; Segi, M.; Furuyama, T.*
    Molecules 2022, 27, 2766.
    DOI: 10.3390/molecules27092766

  • Synthesis of V-shaped fused phthalonitriles and control of their molecular orientation
    Murakami, M.; Maeda, K.; Maeda, H.; Segi, M.; Furuyama, T.*
    Tetrahedron Lett. 2022, 95, 153750.
    DOI: 10.1016/j.tetlet.2022.153750

  • Direct near infrared light-activatable phthalocyanine catalysts
    Katsurayama, Y.; Ikabata, Y.; Maeda, H.; Segi, M.; Nakai, H.; Furuyama, T.*
    Chem. Eur. J. 2022, 28, e202103223.
    DOI: 10.1002/chem.202103223
    Selected as a Hot Paper
    Selected as an Inside Cover

    DOI: 10.1002/chem.202104515

  • Red-light-activatable ruthenium phthalocyanine catalysts
    Ishikawa, Y.; Kameyama, T.; Torimoto, T.; Maeda, H.; Segi, M.; Furuyama, T.*
    Chem. Commun. 2021, 57, 13594-13597.
    DOI: 10.1039/d1cc06307c

  • Direct excitation of triplet state of molecule by enhanced magnetic field of dielectric metasurfaces
    Sugimoto, H.; Hasebe, H.; Furuyama, T.; Fujii, M.
    Small 2021, 17, 2104458.
    DOI: 10.1002/smll.202104458
    Press Release (Kobe Univ., Kanazawa Univ., and JST on 21/10/14)
    日本経済新聞Web版2021年10月15日付で紹介
    北國新聞 2021年10月15日付(第46199号)38面で紹介

  • Synthesis of homo- and heterofunctionalized bay-annulated indigo derivatives and their properties
    Furuyama, T.*; Tamura, D.; Maeda, H.; Segi, M.; Uchiyama, M.
    Dyes Pigments 2021, 193, 109535.
    DOI: 10.1016/j.dyepig.2021.109535

  • Fluorescent-oxaboroles: Synthesis and optical property by sugar recognition
    Nakano, M.; Nakamura, R.; Sumida, Y.; Nagao, K.: Furuyama, T.; Inagaki, F.; Ohmiya, H.
    Chem. Pharm. Bull. 2021, 69, 526-528.
    DOI: 10.1248/cpb.c21-00179

  • Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles
    Tarakanova, E. N.; Trakanov, P. A.; Simakov, A. O.; Furuyama, T.; Kobayashi, N.; Konev, D. V.; Goncharova, O. A.; Trashin, S.; De Wael, K.; Sulimenkov, I. V.; Filatov, V.; Kozlovskiy, V.; Tomilova, L. G.; Stuzhin, P. A.; Pushkarev, V. E.
    Dalton. Trans. 2021, 50, 6245-6255.
    DOI: 10.1039/D1DT00088H

  • Efficiency enhancement of a photocatalytic decarbonylation of an aminocyclopropenone by benzothiophene substitution
    Mishiro, K.; Nomura, M.; Furuyama, T.; Kunishima, M.
    J. Org. Chem. 2021, 86, 3625-3636.
    DOI: 10.1021/acs.joc.0c02997

  • Synthesis of low-symmetry ball-shaped ruthenium complexes and fine-tuning of their optical properties in the visible and NIR region
    Ishikawa, S.; Shimasaki, F.; Maeda, H.; Segi, M.; Furuyama, T.*
    Chem. Lett. 2020, 49, 1394-1398.
    DOI: 10.1246/cl.200557

  • Temperature-dependent changes in the molecular orientation and visible color of phthalocyanine films
    Furuyama, T.*; Uchiyama, S.; Chikamatsu, T.; Horikawa, T.; Maeda, H.; Segi, M.; Takahashi, H.; Taima, T.
    RSC Adv. 2020, 10, 31348-31354.
    DOI: 10.1039/d0ra06273a

  • Photophysical properties of silyl‐substituted stilbene derivatives
    Maeda, H.; Horikoshi, R.; Yamaji, M.; Furuyama, T.; Segi, M.
    Eur. J. Org. Chem. 2020, 3410-3422.
    DOI: 10.1002/ejoc.202000397

  • Synthesis and electronic properties of meso-tetra(3,4,5-trimethoxy)phenyl-porphyrin and -tetrabenzoporphyrin and their phosphorus complexes
    Furuyama, T.*; Takahashi, Y.; Fukumura, T.; Bacilla, A. C. C.; Kobayashi, N.
    J. Porphyrins Phthalocyanines 2020, 24, 105-111.
    DOI: 10.1142/S1088424619500871

  • Effects of substituents on absorption and fluorescence properties of trimethylsilylethynyl- and tert-butylethynyl-pyrenes
    Maeda, H.; Ueno, R.; Furuyama, T.; Segi, M.
    J. Photochem. Photobiol. A 2020, 392, 112428.
    DOI: 10.1016/j.jphotochem.2020.112428

  • One-step synthesis of ball-shaped metal complexes with a main absorption band in the near-IR region
    Furuyama, T.*; Shimasaki, F.; Saikawa, N.; Maeda, H.; Segi, M.
    Sci. Rep. 2019, 9, 16528.
    DOI: 10.1038/s41598-019-53014-7

  • Chemoselective synthesis of aryloxy-substituted phthalocyanines
    Furuyama, T.*; Maeda, K.; Maeda, H.; Segi, M.
    J. Org. Chem. 2019, 84, 14306-14312.
    DOI: 10.1021/acs.joc.9b02126

  • Synthesis, fluorescence properties, and conformational analysis of ether-linked (1,8)pyrenophanes
    Maeda, H.; Geshi, M.; Hirose, K.; Furuyama, T.; Segi, M.
    Tetrahedron 2019, 75, 130512.
    DOI: 10.1016/j.tet.2019.130512

  • (1,3)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions
    Maeda, H.; Nakamura, K.; Furuyama, T.; Segi, M.
    Photochem. Photobiol. Sci. 2019, 18, 2397-2410.
    DOI: 10.1039/c9pp00239a

  • Cationic axial ligands on sulfur substituted silicon(IV) phthalocyanines: Improved hydrophilicity and exceptionally red-shifted absorption into the NIR region
    Furuyama, T.*; Ishii, T.; Ieda, N.; Maeda, H.; Segi, M.; Uchiyama, M.; Nakagawa, H.
    Chem. Commun. 2019, 55, 7311-7314.
    DOI: 10.1039/c9cc03022k
    Selected as a Back Cover (Vol. 55, issue 51)

  • Phototriggered active alkyne generation from cyclopropenones with visible light-responsive photocatalysts
    Mishiro, K.; Kimura, T.; Furuyama, T.; Kunishima, M.
    Org. Lett. 2019, 21, 4101-4105.
    DOI: 10.1021/acs.orglett.9b01280

  • Synthesis, structural and optical properties of tetrabenzoporphyrin complexes bearing four or eight peripheral phenyl groups
    Furuyama, T.*; Okujima, T.; Muramatsu, K.; Takahashi, Y.; Mikami, A.; Fukumura, T.; Mori, S.; Nakae, T.; Takase, M.; Uno, H.; Kobayashi, N.
    Eur. J. Org. Chem. 2019, 3224-3235.
    DOI: 10.1002/ejoc.201900528

  • Extremely photostable electron-deficient phthalocyanines that generate high levels of singlet oxygen
    Furuyama, T.*; Miyaji, Y.; Maeda, K.; Maeda, H.; Segi, M.
    Chem. Eur. J. 2019, 25, 1678-1682.
    DOI: 10.1002/chem.201805082
    Selected as a Hot Paper
    Selected as a Front Cover (Vol. 25, issue 7)
    Featured in Cover Profile
    (Chem. Eur. J. 2019, 25, 1605.)
    DOI: 10.1002/chem.201806336

  • Synthesis and peripheral substituent effects of bay-annulated indigo derivatives
    Furuyama, T.*; Tamura, D.; Maeda, H.; Segi, M.
    Tetrahedron Lett. 2018, 59, 2913-2916.
    DOI: 10.1016/j.tetlet.2018.06.036

  • Electron photoejection from dianion of an expanded phthalocyanine
    Koo, Y. H.; Yanagisawa, R.; Cha, W.-Y.; Furuyama, T.*; Kobayashi, N.; Kim, D.
    J. Porphyrins Phthalocyanines 2018, 22, 437-442.
    DOI: 10.1142/S1088424618500359

  • Changes of phthalocyanine visible color caused by near-IR solvatochromism
    Furuyama, T.*; Uchiyama, S.; Iwamoto, T.; Maeda, H.; Segi, M.
    J. Porphyrins Phthalocyanines 2018, 22, 88-94.
    DOI: 10.1142/S1088424618500098

  • D-A-D type dinitriles with vapor-dependent luminescence in the solid state
    Furuyama, T.*; Shinozaki, J.; Tasso, T. T.; Maeda, H.; Segi, M.; Kobayashi, N.
    Tetrahedron Lett. 2017, 58, 4243-4247.
    DOI: 10.1016/j.tetlet.2017.09.068
    Selected as a Cover Article (Vol. 58, issue 45)

  • Structural, photophysical, and magnetic circular dichroism studies of three rigidified meso-pentafluorophenyl-substituted hexaphyrin analogues
    Ishida, M.; Furuyama, T.; Lim, J. M.; Lee, S.; Zhang, Z.; Ghosh, S. K.; Lynch, V. M.; Lee, C.-H.; Kobayashi, N.; Kim, D.; Sessler, J. L.
    Chem. Eur. J. 2017, 23, 6682-6692.
    DOI: 10.1002/chem.201700759

  • Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes
    Furuyama, T.; Sugiya, Y.; Yoshida, T.; Kobayashi, N.
    J. Porphyrins Phthalocyanines 2016, 20, 1075-1081
    DOI: 10.1142/S1088424616500619

  • Simple primary β-amino alcohol catalyzed enantioselective Diels-Alder reaction of 3-hydroxy-2-pyridones
    Takahashi, T.; Reddy, U. V. S.; Kohari, Y.; Seki, C.; Furuyama, T.; Kobayashi, N.; Okuyama, Y.; Kwon, E.; Uwai, K.; Tokiwa, M.; Takeshita, M.; Nakano H. Tetrahedron Lett. 2016, 57, 5771-5776.
    DOI: 10.1016/j.tetlet.2016.11.030

  • Formation of a trithia[5]helicene in an unexpected photoreaction of a methyl-substituted bis(dithienylethenyl)thiophene through a double sequence of 6π-electrocyclization/aromatization (dehydrogenation/demethylation)
    Yamamoto, A.; Matsui, Y.; Ohta, E.; Ogaki, T.; Sato, H.; Furuyama, T.; Kobayashi, N.; Mizuno, K.; Ikeda, H.
    J. Photochem. Photobiol. A 2016, 331, 48-55.
    DOI: 10.1016/j.jphotochem.2015.10.012

  • Double-decker bis(tetradiazepinoporphyrazinato) rare earth complexes: Crucial role of intramolecular hydrogen bonding
    Tarakanova, E. N.; Trashin, S.; Simakov, A. O.; Furuyama, T.; Dzuban, A. V.; Inasaridze, L. N.; Tarakanov, P. A.; Troshin, P.; Pushkarev, V.; Kobayashi, N.; Tomilova, L. B.
    Dalton Trans. 2016, 45, 12041-12052.
    DOI: 10.1039/c6dt01779g

  • Synthesis, optical properties, and electronic structures of tetrakis(pentafluorophenyl)tetrathiaisophlorin dioxide
    Mishra, V. L.; Furuyama, T.; Kobayashi, N.; Goto, K.; Miyazaki, T.; Yang, J.-S.; Shinmyozu, T.
    Chem. Eur. J. 2016, 22, 9190-9197.
    DOI: 10.1002/chem.201505079

  • Preparation, optical and electrochemical properties, and molecular orbital calculations of tetraazaporphyrinato ruthenium (II) bis(4-methylpyridine) fused with one to four diphenylthiophene units
    Kimura, T.; Murakami, N.; Suzuki, E.; Furuyama, T.; Nakahodo, T.; Fujihara, H.; Kobayashi, N.
    J. Inorg. Biochem. 2016, 158, 35-44.
    DOI: 10.1016/j.jinorgbio.2016.01.010

  • Synthesis and Photophysical Investigation of Tetraazaporphyrin Substituted with Aggregation-Induced Emission (AIE) Active Moieties
    Tasso, T. T.; Furuyama, T.; Mack, J.; Nyokong, T.; Kobayashi, N.
    Eur. J. Inorg. Chem. 2015, 5516-5522.
    DOI: 10.1002/ejic.201500726

  • A Bottom-up Synthesis of Antiaromatic Expanded Phthalocyanines: Pentabenzotriazasmaragdyrins, i.e. Norcorroles of Superphthalocyanines
    Furuyama, T.; Sato, T.; Kobayashi, N.
    J. Am. Chem. Soc. 2015, 137, 13788-13791.
    DOI: 10.1021/jacs.5b09853
    Highlighted in “Chem-Station”

  • Solution-Cast Monolayers of Cobalt Crown Ether Phthalocyanine on Highly Ordered Pyrolytic Graphite
    Lu, H.; Kwak, I.; Park, J. H.; O’Neill, K.; Furuyama, T.; Kobayashi, N.; Seabaugh, A.; Kummel, A.; Fullerton-Shirey, S. K.
    J. Phys. Chem. C 2015, 119, 21992-22000.
    DOI: 10.1021/acs.jpcc.5b05233

  • Fluorescence Enhancement of Tetraazaporphyrins by Use of Bulky Substituent Effects
    Yoshida, T.; Furuyama, T.; Asai, M.; Kobayashi, N.
    Chem. Lett. 2015, 44, 1056-1058.
    DOI: 10.1246/cl.150304

  • An Extremely Air-Stable 19π Porphyrinoid
    Yoshida, T.; Zhou, W.; Furuyama, T.*; Leznoff, D. B.; Kobayashi, N.
    J. Am. Chem. Soc. 2015, 137, 9258-9261.
    DOI: 10.1021/jacs.5b05781

  • Reducing Zirconium(IV) Phthalocyanines and the Structure of a Pc  –Zr Complex
    Zhou, W.; Platel, R. H.; Tasso, T. T.; Furuyama, T.; Kobayashi, N.; Leznoff, D. B.
    Dalton. Trans. 2015, 44, 13955-13961.
    DOI: 10.1039/c5dt01778e

  • Stable iso-Bacteriochlorin Mimics from Porpholactone: Effect of β-oxazolone Moiety on the Frontier π-Molecular Orbitals
    Yu, Y.; Furuyama, T.; Tang, J.; Wu, Z.-Y.; Chen, J.-Z.; Kobayashi, N.; Zhang, J.-L.
    Inorg. Chem. Front. 2015, 2, 671-677.
    DOI: 10.1039/c5qi00054h

  • Structural Changes in Non-Planar Octaaryl Substituted Phthalocyanine Phosphorus Complexes
    Furuyama, T.; Harako, R.; Kobayashi, N.
    J. Porphyrin Phthalocyanines 2015, 19, 500-509.
    DOI: 10.1142/S1088424615500364

  • Synthesis and Spectral Properties of Nonclassical Binuclear Thienoporphyrazines
    Dubinina, T. V.; Borisova, N. E.; Sedova, M. V.; Tomilova, L. B.; Furuyama, T.; Kobayashi, N.
    Dyes Pigments 2015, 117, 1-6.
    DOI: 10.1016/j.dyepig.2015.01.023

  • Synthesis and Optical Properties of Tetraazaporphyrin Phosphorus(V) Complexes with Electron-Rich Heteroatoms
    Yoshida, T.; Furuyama, T.; Kobayashi, N.
    Tetrahedron Lett. 2015, 56, 1671-1674.
    DOI: 10.1016/j.tetlet.2015.02.033

  • Metallophthalocyanin-ocenes: Scandium Phthalocyanines with an η5-bound Cp Ring
    Platel, R. H.; Tasso, T. T.; Zhou, W.; Furuyama, T.; Kobayashi, N.: Leznoff, D. B.
    Chem. Commun. 2015, 51, 5986-5989.
    DOI: 10.1039/c5cc00237k

  • Dinitriles Having AIE-Active Moieties: Synthesis, E/Z Isomerization and Fluorescence Properties
    Tasso, T. T.; Furuyama, T.; Kobayashi, N.
    Chem. Eur. J. 2015, 21, 4817-4824.
    DOI: 10.1002/chem.201406128
    Highlighted as “ACS Noteworthy Chemistry”

  • Optical, Electrochemical, and Magnetic Properties of Pyrrole- and Thiophene-Bridged 5,15-Diazaporphyrin Dimers
    Omomo, S.; Maruyama, Y.; Furukawa, K.; Furuyama, T.; Nakano, H.; Kobayashi, N.; Matano, Y.
    Chem. Eur. J. 2015, 21, 2003-2010.
    DOI: 10.1002/chem.201405482

  • Control of Absorption Properties of Tetraazaporphyrin Group 15 Complexes by Modification of their Axial Ligands
    Furuyama, T.; Asai, M.; Kobayashi, N.
    Chem. Commun. 2014, 50, 15101-15104.
    DOI: 10.1039/c4cc07408d

  • Enantioselective Diels-Alder Reaction of 1,2-Dihydropyridines with Aldehydes using β-Amino Alcohol Organocatalyst
    Kohari, Y.; Okuyama, Y.; Kwon, E.; Furuyama, T.; Kobayashi, N.; Otuki, T.; Kumagai, J.; Seki, C.; Uwai, K.; Dai, G.; Iwasa, T.; Nakano, H.
    J. Org. Chem. 2014, 79, 9500-9511.
    DOI: 10.1021/jo501433c

  • Synthesis of New Chlorin   Trimethyl and Protoporphyrin IX Dimethyl Ester Derivatives and Their Photophysical and Electrochemical Characterizations
    Menezes, J. C. J. M. D. S.; Faustino, M. A. F.; de Oliveira, K. T.; Uliana, M. P.; Ferreira, V. F.; Hackbarth, S.; Röder, B.; Tasso, T. T.; Furuyama, T.; Kobayashi, N.; Silva, A. M. S.; Neves, M. G. P. M. S.; Cavaleiro, J. A. S.
    Chem. Eur. J. 2014, 20, 13644-13655.
    DOI: 10.1002/chem.201403214

  • Synthesis of Tetrabenzotriazacorrole-Subphthalocyanine µ-Oxo Triad
    Furuyama, T.; Sugiya, Y.; Kobayashi, N.
    Macroheterocycles 2014, 7, 139-144.
    DOI: 10.6060/mhc140488k

  • Synthesis and Spectroscopic Properties of Chiral Binaphthyl-Linked Subphthalocyanines
    Zhao, L.; Wang, K.; Furuyama, T.; Jiang, J.; Kobayashi, N.
    Chem. Commun. 2014, 50, 7663-7665.
    DOI: 10.1039/c4cc03426k

  • High Diastereoselection of Dissymmetric Capsule by Chiral Guest Complexation
    Tsunoda, Y.; Fukuta, K.; Imamura, T.; Sekiya, R.; Furuyama, T.; Kobayashi, N.; Haino, T.
    Angew. Chem. Int. Ed. 2014, 53, 7243-7247.
    DOI: 10.1002/anie.201403721

  • Synthesis and Characterization of Aza-Bridged Thiophene-Pyrrole Dyads and Their Isomers
    Furuyama, T.; Noguchi, D.; Suzuki, Y.; Kobayashi, N.
    Can. J. Chem. 2014, 92, 765-770.
    DOI: 10.1139/cjc-2014-0039

  • Phosphorus(V) Tetraazaporphyrins: Porphyrinoids Showing an Exceptionally Strong CT Band between the Soret and Q Bands
    Furuyama, T.; Yoshida, T.; Hashizume, D.; Kobayashi, N.
    Chem. Sci. 2014, 5, 2466-2474.
    DOI: 10.1039/c4sc00569d

  • Synthesis of Tetrabenzotriazacorrole µ-Oxo Dimer and Investigation of Its Stacking Effect
    Furuyama, T.; Sugiya, Y.; Kobayashi, N.
    Chem. Commun. 2014, 50, 4312-4314.
    DOI: 10.1039/c4cc01115e

  • An Exemplary Relationship between the Extent of Cofacial Aggregation and Fluorescence Quantum Yield as Exhibited by Quaternized Amphiphilic Phthalocyanines
    Tasso, T. T.; Yamasaki, Y.; Furuyama, T.; Kobayashi, N.
    Dalton Trans. 2014, 43, 5886-5892.
    DOI: 10.1039/c4dt00195h

  • Design, Synthesis and Properties of Phthalocyanine Complexes with Main-Group Elements Showing Main Absorption and Fluorescence beyond 1000 nm
    Furuyama, T.; Satoh, K.; Kushiya, T.; Kobayashi, N.
    J. Am. Chem. Soc. 2014, 136, 765-776.
    DOI: 10.1021/ja411016f

  • Absorption and Electrochemical Properties of Cobalt and Iron Phthalocyanines and Their Quaternized Derivatives: Aggregation Equilibrium and Oxygen Reduction Electrocatalysis
    Tasso, T. T.; Furuyama, T.; Kobayashi, N.
    Inorg. Chem. 2013, 52, 9206-9215.
    DOI: 10.1021/ic4002048

  • Superazaporphyrins: Meso-Pentaazapentaphyrins and One of Their Low-Symmetry Derivatives
    Furuyama, T.; Ogura, Y.; Yoza, K.; Kobayashi, N.
    Angew. Chem. Int. Ed. 2012, 51, 11110-11114.
    DOI: 10.1002/anie.201203191

  • A Zinc Gable Phthalocyanine and a Derived Planar Bis-phthalocyanine Containing a Shared Anthracene Unit
    Asano, Y.; Sato, J.; Furuyama, T.; Kobayashi, N.
    Chem. Commun. 2012, 48, 4365-4367.
    DOI: 10.1039/C2CC31264F

  • Aluminepin: Aluminum Analogues of Borepin and Gallepin
    Yoshida, K.; Furuyama, T.; Wang, C.; Muranaka, A.; Hashizume, D.; Yasuike, S.; Uchiyama, M.
    J. Org. Chem. 2012, 77, 729-732.
    DOI: 10.1021/jo201992q

  • Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center
    Jiang, X.-D.; Zhang, J.; Furuyama, T.; Zhao, W.
    Org. Lett. 2012, 14, 248-251.
    DOI: 10.1021/ol2030229

  • Rationally Designed Phthalocyanines Having Their Main Absorption Band beyond 1000 nm
    Kobayashi, N.; Furuyama, T.; Satoh, K.
    J. Am. Chem. Soc. 2011, 133, 19642-19645.
    DOI: 10.1021/ja208481q

  • Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches
    Takaishi, K.; Kawamoto, M.; Tsubaki, K.; Furuyama, T.; Muranaka, A.; Uchiyama, M.
    Chem. Eur. J. 2011, 17, 1778-1782.
    DOI: 10.1002/chem.201003087

  • Calix[3]amide-based Anion Receptors: High Affinity for Fluoride Ion and Twisted Binding Model
    Katagiri, K.; Furuyama, T.; Masu, H.; Kato, T.; Matsumura, M.; Uchiyama, M.; Tanatani, A.; Tominaga, M.; Kagechika, H.; Yamaguchi, K.; Azumaya, I.
    Supramolecular Chemistry 2011, 23, 125-130.
    DOI: 10.1080/10610278.2010.514909

  • 1,4-Addition of Bis(iodozincio)methane to ɑ,β-Unsaturated Ketones: Chemical and Theoretical/Computational Studies
    Sada, M.; Furuyama, T.; Komagawa, S.; Uchiyama, M.; Matsubara, S.
    Chem. Eur. J. 2010, 16, 10474-10481.
    DOI: 10.1002/chem.201000738

  • Reaction Mechanism for the LiCl-Mediated Directed Zinc Insertion: A Computational and Experimental Study
    Liu, C.-Y.; Wang, X.; Furuyama, T.; Yasuike, S.; Muranaka, A.; Morokuma, K.; Uchiyama, M.
    Chem. Eur. J. 2010, 16, 1780-1784.
    DOI: 10.1002/chem.200902957

  • Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB  Monomer Making Use of Changed Substituent Effects
    Ohta, Y.; Fujii, S.; Yokoyama, A.; Furuyama, T.; Uchiyama, M.; Yokozawa, T.
    Angew. Chem. Int. Ed. 2009, 48, 5942-5945.
    DOI: 10.1002/anie.200901714

  • Application of the Perimeter Model to the Assignment of the Electronic Absorption Spectra of Gold(III) Hexaphyrins with [4n+2] and [4n] π-Electron Systems
    Muranaka, A.; Matsushita, O.; Yoshida, K.; Mori, S.; Suzuki, M.; Furuyama, T.; Uchiyama, M.; Osuka, A.; Kobayashi, N.
    Chem. Eur. J. 2009, 15, 3744-3751.
    DOI: 10.1002/chem.200801742

  • Development of Highly Chemoselective Bulky Zincate Complex, tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis
    Furuyama, T.; Yonehara, M.; Arimoto, S.; Kobayashi, M.; Matsumoto, Y.; Uchiyama, M.
    Chem. Eur. J. 2008, 14, 10348-10356.
    DOI: 10.1002/chem.200800536

  • Structural Development of Benzhydrol-Type 1’-Acetoxychavicol Acetate (ACA) Analogs as Human Leukemia Cell-Browth Inhibitors Based on Quantitative Structure-Activity Relationship (QSAR) Analysis
    Misawa, T.; Aoyama, H.; Furuyama, T.; Dodo, K.; Sagawa, M.; Miyachi, H.; Kizaki, M.; Hashimoto, Y.
    Chem. Pharm. Bull. 2008, 56, 1490-1495.
    DOI: 10.1248/cpb.56.1490

  • Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP-Zn-ate): New Approaches to Multisubstituted Benzenes
    Uchiyama, M.; Kobayashi, Y.; Furuyama, T.; Nakamura, S.; Kajihara, Y.; Miyoshi, T.; Sakamoto, T.; Kondo, Y.; Morokuma, K.
    J. Am. Chem. Soc. 2008, 130, 472-480.
    DOI: 10.1021/ja071268u

  • Reaction Pathway of Conjugate Addition of Lithium Organozincates to s-trans-Enones
    Uchiyama, M.; Nakamura, S.; Furuyama, T.; Nakamura, E.; Morokuma, K.
    J. Am. Chem. Soc. 2007, 129, 13360-13361.
    DOI: 10.1021/ja070123k

  • Toward a Protecting-Group-Free Halogen-Metal Exchange Reaction: Practical, Chemoselective Metalation of Functionalized Aromatic Halides Using Dianion-Type Zincate, tBu4ZnLi2 
    Uchiyama, M.; Furuyama, T.; Kobayashi, M.; Matsumoto, Y.; Tanaka, K.
    J. Am. Chem. Soc. 2006, 128, 8404-8405.
    DOI: 10.1021/ja058246x

  • Structure and Reaction Pathway of TMP-Zincate: Amido Base or Alkyl Base?
    Uchiyama, M.; Matsumoto, Y.; Nobuto, D.; Furuyama, T.; Yamaguchi, K.; Morokuma, K.
    J. Am. Chem. Soc. 2006, 128, 8748-8750.
    DOI: 10.1021/ja060489h

  • Inductive Effect-Assisted Chain-Growth Polycondensation. Synthetic Development from para- to meta-Substituted Aromatic Polyamides with Low Polydispersities
    Sugi, R.; Yokoyama, A.; Furuyama, T.; Uchiyama, M.; Yokozawa, T.
    J. Am. Chem. Soc. 2005, 127, 10172-10173.
    DOI: 10.1021/ja052566z



     

1,5

6

2

総説・解説記事

  • 近赤外光反応制御を目指した有機色素の合成化学(総合論文)
    古山渓行
    有機合成化学協会誌2024, 82, 989-1000.
    DOI: 10.1142/S1088424622300014

  • Development of controlled reactions using an element-based design of azaporphyrinoid materials
    Furuyama, T.
    J. Porphyrins Phthalocyanines 2022, 26, 790-806.
    DOI: 10.1142/S1088424622300014
    (Award Account for SPP/JPP Young Investigator Award)

  • 近赤外光活用を目指した有機機能性色素の合成技術(解説記事)
    古山渓行
    ファインケミカル2021, 50 (9), 12-17,

  • 近赤外光と強く相互作用する有機金属錯体の開発(解説記事)
    古山渓行
    光化学2021, 52, 25-28.

  • 親水性ケイ素フタロシアニンの近赤外光線力学療法への応用(解説記事)
    石井孝知、古山渓行
    マテリアルステージ2021 (1), 80-84.

  • 近赤外光を活用できる有機金属錯体の合成技術(解説記事)
    古山渓行
    オプトロニクス2020, 458, 134-139.

  • 典型元素を活用するフタロシアニン光材料の合成(解説記事)
    古山渓行
    化学工業2019, 70, 169-174.

  • 機能性π共役化合物の設計・合成と近赤外光利活用への挑戦
    古山 渓行
    薬学雑誌2018, 138, 731-742.
    DOI: 10.1248/yakushi.17-00233.
    (平成29年度日本薬学会奨励賞受賞記念総説)

  • Azaporphyrin Phosphorus(V) Complexes: Synthesis, Structure, and Modification of Optical Properties (Perspective)
    Furuyama, T.; Kobayashi, N.
    Phys. Chem. Chem. Phys. 2017, 19, 15596-15612.
    DOI: 10.1039/c7cp02155k.
    Featured in “2017 PCCP HOT Articles”

  • 高原子価リンを活用するアザポルフィリン誘導体のデザイン・合成・機能開発(総合論文)
    古山 渓行、小林 長夫
    有機合成化学協会誌2015, 73, 833-843.
    DOI: 10.5059/yukigoseikyokaishi.73.833.

  • 高原子価リンを活用したアザポルフィリン類の光特性制御(解説記事)
    古山 渓行
    化学と工業2015, 68, 644-645.

  • 近赤外光の有効利用に向けて—合理的にデザインされたフタロシアニン誘導体(解説記事)
    小林 長夫、古山 渓行
    化学2013, 68, 66-67. 

  • 歪んだ3員環を自在に操る新しい有機合成(解説記事)
    古山 渓行
    ファルマシア2009, 45, 1250.

  • 酸化過程を経由する新しいアミド結合形成反応の新展開(解説記事)
    古山 渓行
    有機合成化学協会誌2008, 66, 1005-1006.

特許

  • フタロシアニン系化合物、膜及びフタロシアニン系化合物の製造方法
    古山 渓行、中谷 友哉、前田 和哉、前多 肇、千木 昌人
    特開2023-066025

  • 金属錯体及び金属錯体の製造方法
    古山 渓行、島崎 史佳、前多 肇、千木 昌人
    特許第7064764号

  • 組成物、近赤外光電変換素子および撮像素子
    飯島 浩章、平出 雅哉、中田 学、古山 渓行
    特許第6767695号

  • 赤外吸収フタロシアニン
    小林 長夫、古山 渓行、佐藤 皓、辻 良太郎、太和田 善久
    特開 2013-103911

  • 新規な化合物、その合成中間体及びそれらの製造方法
    内山 真伸、古山 渓行、吉田 健吾
    特開2010-202616

依頼・招待講演

  • Functional Integration of Near-Infrared-Light-Absorbing Ball-Shaped Metal Complexes(Invited Oral)
    13th International Conference on Porphyrin and Phthalocyanines (ICPP-13)(Buffalo, USA)
    2024年6月24日

  • 近赤外光を活用できる有機材料の合成と機能開発(依頼講演)
    第1回金沢大学ナノマテリアル研究所シンポジウム(石川県金沢市)
    2023年12月7日

  • 光反応制御を目指した近赤外色素合成化学(招待講演)
    九州大学大学院総合理工学研究院・理学研究院特別講演会(福岡県福岡市)
    2023年10月30, 31日

  • 近赤外NIR-II領域を活用できる新材料(依頼講演)
    JST戦略的創造研究推進事業① 〜さきがけ研究領域「反応制御」〜 新技術説明会(オンライン)
    2023年10月20日
    ​発表詳細・資料
    講演動画

  • 近赤外光反応制御が拓く有機合成化学(招待講演)
    神戸大学大学院工学系研究科講演会(兵庫県神戸市)

    2023年9月15日

  • Design of Controlled Near-infrared Light-responsive Photocatalysts(Invited Oral)
    2023 Taiwan-Japan Symposium on Reaction Control (TJSReC)(Hsinchu, Taiwan)
    2023年7月29日

  • Organic Reactions Using Near-infrared Light Mediated Controlled Photocatalysts(Invited Oral)
    18th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23)(Shiga, Japan)
    2023年6月10日

  • 近赤外光反応制御を指向した有機材料の開発(招待講演)
    新潟大学コアステーション「ユビキタスグリーンケミカルエネルギー連携教育研究センター」第13回研究シンポジウム(新潟県新潟市)
    2023年3月14日

  • Development of Controlled Reactions Using Phthalocyanine-based Materials(Award Lecture)
    12th International Conference on Porphyrin and Phthalocyanines (ICPP-12)(Madrid, Spain)
    2022年7月13日

  • Photocatalysis Mediated by Far-red Light(Keynote Lecture)
    6th International Conference on Catalysis and Chemical Engineering (CCE-2022)(Online)
    2022年2月23日

  • 光触媒の能動的制御による近赤外光合成プロセスの開発(招待講演)
    さきがけ「電子やイオン等の能動的制御と反応」領域 オンライン公開シンポジウム(1期生研究成果発表会) (オンライン)
    2022年1月8日

  • 機能性フタロシアニンの開発(招待講演)
    企業向け社内講演会
    2021年12月8日

  • 有機近赤外色素の合成技術・創成・機能開発(招待講演)
    第6回「生体適合化学の進歩」インタラクティブフォーラム(オンライン)
    2021年9月22日
    講演動画

  • Axial ligand effects on sulfur-substituted silicon(IV) phthalocyanines(Invited Oral)
    11th International Conference on Porphyrin and Phthalocyanines (ICPP-11)(Online)
    2021年6月29日

  • 精密有機合成技術に基づく近赤外色素材料の開発と応用(招待講演)
    金沢大学先端科学・イノベーション推進機構協力会 第16回金沢大学研究室見学会(石川県金沢市)
    2021年2月19日

  • 近赤外光を活用できる機能性色素の精密有機合成技術(招待講演)
    岡山大学次世代研究育成グループ「精密有機合成に基づく高機能性有機色素の開発」講演会(岡山県岡山市)
    2020年2月7日

  • 近赤外域に強い吸収を持ち、光波長特性を制御可能な有機色素材料の開発(招待講演)
    企業向け社内講演会
    2020年1月30日

  • 近赤外光を活用できる有機ルテニウム錯体の合成技術(依頼講演)
    2019 金沢大学新技術説明会(東京都千代田区)
    2019年8月22日
    発表詳細・資料

  • 電気・光特性を自在に活用できる有機材料の開発(招待講演)
    2019年度電気化学会北陸支部春季(石川)大会(石川県金沢市)
    2019年6月14日

  • Synthesis of ball-shaped metal complexes with a main absorption band in the near-IR region(Invited Oral)
    7th Geogian Bay International Conference on Bioinorganic Chemistry (CanBIC-7)(Parry Sound, Canada)
    2019年5月22日

  • 分子の「かたち」から「しくみ」を見通す有機化学(企画講演)
    国際科学技術財団 第320回やさしい科学技術セミナー(石川県金沢市)
    2018年11月18日
    講演動画

  • 元素の特性を利用した有機近赤外光材料の開発(招待講演)
    第3回有機若手ワークショップ(京都府京都市)
    2018年11月8日

  • アザポルフィリンを活用する近赤外光材料の開発(依頼講演)
    第38回光化学若手の会(福岡県福岡市)
    2017年6月17日

  • 機能性π共役化合物の設計・合成と近赤外光利活用への挑戦(日本薬学会奨励賞受賞講演)
    日本薬学会第137年会(宮城県仙台市)
    2017年3月25日

  • 元素特性を活用したアザポルフィリン光材料の開発(依頼講演)
    第5回化学フロンティア研究会(高知県高知市)
    2016年7月31日

  • An air-stable 19π azaporphyrinoid radical(Invited Oral)
    9th International Conference on Porphyrin and Phthalocyanines (ICPP-9)(Nanjing, China)
    2016年7月4日

  • 元素の特性を活用したアザポルフィリン類の合成・光物性制御(若い世代の特別講演)
    日本化学会第95春季年会(千葉県船橋市)
    2015年3月26日

  • フタロシアニン典型元素錯体の開発と性質(依頼講演)
    第30回無機・分析化学コロキウム(宮城県大崎市)
    2013年6月1日

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