原著論文
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Harnessing dye-induced photothermal confinement in lipid membranes: A Path to NIR-modulated artificial synaptic vesicles
Sarker, S. R.; Yamazaki, T.; Sou, K.; Takemura, I.; Kurita, Y.; Nomura, K.; Ichimura, M.; Suzuki, T.; Kai, A.; Araki, T.; Hattori, S.; Furuyama, T.; Chang, Y.-T.; Kiya, T.; Arai, S.
bioRxiv
DOI: 10.1101/2024.07.20.604262 -
Near-infrared-light-activatable proximity labeling of bead-binding proteins
Nakane, K.; Hoshino, Y.; Dodo, K.; Tomoshige, S.; Ishikawa, M.; Furuyama, T.*; Sato, S.
ChemRxiv
DOI: 10.26434/chemrxiv-2023-443cj -
Induced of axial chirality in near-infrared-absorbing ball-shaped ruthenium complexes
Shinokubo, Y.; Arai, R.; Nishimura, T.; Maeda, K.; Maeda, H.; Segi, M.; Furuyama, T.*
J. Photochem. Photobiol. A 2025, 459, 116089.
DOI: 10.1016/j.photochem.2024.116089 -
Phototriggered generation of ynol ethers and their rearrangement to ketenes
Mogami, S.; Baba, M.; Furuyama, T.; Kunishima, M.; Mishiro, K.
J. Org. Chem. 2024, 89, 10709-10718.
DOI: 10.1021/acs.joc.4c00947 -
Red-light-driven bifunctionalization of styrene derivatives
Kai, U.; Katsurayama, Y.; Nishida, R.; Kameyama, T.; Torimoto, T.; Furuyama, T.*
J. Org. Chem. 2024, 89, 8178-8184.
DOI: 10.1021/acs.joc.4c00889 -
Dehydro[12]- and [18]annulene-fused ball-shaped ruthenium complex oligomers: Synthesis, aromatic/antiaromatic effect, and symmetry for near-infrared optical properties
Ishikawa, S.; Maeda, H.; Segi, M.; Furuyama, T.*
Chem. Eur. J. 2024, 30, e202400407.
DOI: 10.1002/chem.202400407
Selected as a Hot Paper -
Selective formation of Cu active sites with different coordination states on pseudo-spinel CuAl2O4 and their NO reduction catalysis
Okuda, A.; Furuyama, T.; Sakai, T.; Machida, M.; Yoshida, H.
ACS Omega 2024, 9, 11950-11957.
DOI: 10.1021/acsomega.3c09704 -
Phosphorus(V) tetraazaporphyrin with an intense, broad CT band in the near-IR region
Yoshida, T.; Okada, Y.; Namikawa, T.; Furuyama, T.*; Kamada, K.; Kobayashi, N.
Org. Lett. 2024, 26, 1931-1935.
DOI: 10.1021/acs.orglett.4c000298 -
Phototriggered butenolide formation from a cyclobutenedione and an acidic nucleophile
Mishiro, K.; Sesumi, A.; Fujii, T.; Furuyama, T.; Kunishima, M.
Org. Lett. 2024, 26, 380-384.
DOI: 10.1021/acs.orglett.3c04054 -
Photosensitizing metasurface empowered by enhanced magnetic field of toroidal dipole resonance
Hasebe, H.; Sugimoto, H.; Katsurayama, Y.; Furuyama, T.; Fujii, M.
Small 2023, 19, 20232519.
DOI: 10.1002/smll.202302519 -
Synthesis and photophysical properties of subphthalocyanine substituted with tetraphenylethylene moieties
Furuyama, T.*; Shitanda, S.; Fukumura, T.; Kobayashi, N.
J. Porphyrins Phthalocyanines 2023, 27, 1156-1163.
DOI: 10.1142/S1088424623500591 -
Decreasing the aggregation and ligand redox potential of metallophthalocyanines through branched ether functionalization
McKearney, D.; Zhou, W.; Scollon, M.; Furuyama, T.*; Williams, V. E.; Leznoff, D. B.
J. Porphyrins Phthalocyanines 2023, 27, 452-462.
DOI: 10.1142/S1088424623500141 -
Rational design of functionalized near-infrared absorbing phthalocyanines by three-component coupling strategy
Iwamoto, T.; Maeda, H.; Segi, M.; Furuyama, T.*
J. Porphyrins Phthalocyanines 2023, 27, 218-225.
DOI: 10.1142/S1088424622300063 -
(1,6)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions. Formation of sandwich, dumbbell, and pseudorotaxane complexes
Maeda, H.; Saito, G.; Furuyama, T.; Segi, M.
New. J. Chem. 2023, 47, 1388-1400.
DOI: 10.1039/D2NJ04790J -
Regioselective rearrangement reactions of naphthyl naphthylmethyl ethers by using Lewis acids or UV light irradiation
Maeda, H.; Nakamura S.; Furuyama, T.; Segi, M.
J. Mol. Struct. 2023, 1274, 134450.
DOI: 10.1016/j.molstruc.2022.134450 -
Synthesis of 3-oxatricyclo[7.2.0.0 ]undeca-7,10-dienes through intramolecular photocycloaddition reactions of alkenes to 1,8 a-position of naphthalene ring
Maeda, H.; Kubo, Y.; Nakashima, R.; Mizuno, K.; Furuyama, T.; Segi, M.
Eur. J. Org. Chem. 2022, 45, e202201051.
DOI: 10.1002/ejoc.202201051 -
Cationic axial ligand effects on sulfur-substituted subphthalocyanines
Ogura, Y.; Nakano, M.; Maeda, H.; Segi, M.; Furuyama, T.*
Molecules 2022, 27, 2766.
DOI: 10.3390/molecules27092766 -
Synthesis of V-shaped fused phthalonitriles and control of their molecular orientation
Murakami, M.; Maeda, K.; Maeda, H.; Segi, M.; Furuyama, T.*
Tetrahedron Lett. 2022, 95, 153750.
DOI: 10.1016/j.tetlet.2022.153750 -
Direct near infrared light-activatable phthalocyanine catalysts
Katsurayama, Y.; Ikabata, Y.; Maeda, H.; Segi, M.; Nakai, H.; Furuyama, T.*
Chem. Eur. J. 2022, 28, e202103223.
DOI: 10.1002/chem.202103223
Selected as a Hot Paper
Selected as an Inside Cover
DOI: 10.1002/chem.202104515 -
Red-light-activatable ruthenium phthalocyanine catalysts
Ishikawa, Y.; Kameyama, T.; Torimoto, T.; Maeda, H.; Segi, M.; Furuyama, T.*
Chem. Commun. 2021, 57, 13594-13597.
DOI: 10.1039/d1cc06307c -
Direct excitation of triplet state of molecule by enhanced magnetic field of dielectric metasurfaces
Sugimoto, H.; Hasebe, H.; Furuyama, T.; Fujii, M.
Small 2021, 17, 2104458.
DOI: 10.1002/smll.202104458
Press Release (Kobe Univ., Kanazawa Univ., and JST on 21/10/14)
日本経済新聞Web版2021年10月15日付で紹介
北國新聞 2021年10月15日付(第46199号)38面で紹介 -
Synthesis of homo- and heterofunctionalized bay-annulated indigo derivatives and their properties
Furuyama, T.*; Tamura, D.; Maeda, H.; Segi, M.; Uchiyama, M.
Dyes Pigments 2021, 193, 109535.
DOI: 10.1016/j.dyepig.2021.109535 -
Fluorescent-oxaboroles: Synthesis and optical property by sugar recognition
Nakano, M.; Nakamura, R.; Sumida, Y.; Nagao, K.: Furuyama, T.; Inagaki, F.; Ohmiya, H.
Chem. Pharm. Bull. 2021, 69, 526-528.
DOI: 10.1248/cpb.c21-00179 -
Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles
Tarakanova, E. N.; Trakanov, P. A.; Simakov, A. O.; Furuyama, T.; Kobayashi, N.; Konev, D. V.; Goncharova, O. A.; Trashin, S.; De Wael, K.; Sulimenkov, I. V.; Filatov, V.; Kozlovskiy, V.; Tomilova, L. G.; Stuzhin, P. A.; Pushkarev, V. E.
Dalton. Trans. 2021, 50, 6245-6255.
DOI: 10.1039/D1DT00088H -
Efficiency enhancement of a photocatalytic decarbonylation of an aminocyclopropenone by benzothiophene substitution
Mishiro, K.; Nomura, M.; Furuyama, T.; Kunishima, M.
J. Org. Chem. 2021, 86, 3625-3636.
DOI: 10.1021/acs.joc.0c02997 -
Synthesis of low-symmetry ball-shaped ruthenium complexes and fine-tuning of their optical properties in the visible and NIR region
Ishikawa, S.; Shimasaki, F.; Maeda, H.; Segi, M.; Furuyama, T.*
Chem. Lett. 2020, 49, 1394-1398.
DOI: 10.1246/cl.200557 -
Temperature-dependent changes in the molecular orientation and visible color of phthalocyanine films
Furuyama, T.*; Uchiyama, S.; Chikamatsu, T.; Horikawa, T.; Maeda, H.; Segi, M.; Takahashi, H.; Taima, T.
RSC Adv. 2020, 10, 31348-31354.
DOI: 10.1039/d0ra06273a -
Photophysical properties of silyl‐substituted stilbene derivatives
Maeda, H.; Horikoshi, R.; Yamaji, M.; Furuyama, T.; Segi, M.
Eur. J. Org. Chem. 2020, 3410-3422.
DOI: 10.1002/ejoc.202000397 -
Synthesis and electronic properties of meso-tetra(3,4,5-trimethoxy)phenyl-porphyrin and -tetrabenzoporphyrin and their phosphorus complexes
Furuyama, T.*; Takahashi, Y.; Fukumura, T.; Bacilla, A. C. C.; Kobayashi, N.
J. Porphyrins Phthalocyanines 2020, 24, 105-111.
DOI: 10.1142/S1088424619500871 -
Effects of substituents on absorption and fluorescence properties of trimethylsilylethynyl- and tert-butylethynyl-pyrenes
Maeda, H.; Ueno, R.; Furuyama, T.; Segi, M.
J. Photochem. Photobiol. A 2020, 392, 112428.
DOI: 10.1016/j.jphotochem.2020.112428 -
One-step synthesis of ball-shaped metal complexes with a main absorption band in the near-IR region
Furuyama, T.*; Shimasaki, F.; Saikawa, N.; Maeda, H.; Segi, M.
Sci. Rep. 2019, 9, 16528.
DOI: 10.1038/s41598-019-53014-7 -
Chemoselective synthesis of aryloxy-substituted phthalocyanines
Furuyama, T.*; Maeda, K.; Maeda, H.; Segi, M.
J. Org. Chem. 2019, 84, 14306-14312.
DOI: 10.1021/acs.joc.9b02126 -
Synthesis, fluorescence properties, and conformational analysis of ether-linked (1,8)pyrenophanes
Maeda, H.; Geshi, M.; Hirose, K.; Furuyama, T.; Segi, M.
Tetrahedron 2019, 75, 130512.
DOI: 10.1016/j.tet.2019.130512 -
(1,3)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions
Maeda, H.; Nakamura, K.; Furuyama, T.; Segi, M.
Photochem. Photobiol. Sci. 2019, 18, 2397-2410.
DOI: 10.1039/c9pp00239a -
Cationic axial ligands on sulfur substituted silicon(IV) phthalocyanines: Improved hydrophilicity and exceptionally red-shifted absorption into the NIR region
Furuyama, T.*; Ishii, T.; Ieda, N.; Maeda, H.; Segi, M.; Uchiyama, M.; Nakagawa, H.
Chem. Commun. 2019, 55, 7311-7314.
DOI: 10.1039/c9cc03022k
Selected as a Back Cover (Vol. 55, issue 51) -
Phototriggered active alkyne generation from cyclopropenones with visible light-responsive photocatalysts
Mishiro, K.; Kimura, T.; Furuyama, T.; Kunishima, M.
Org. Lett. 2019, 21, 4101-4105.
DOI: 10.1021/acs.orglett.9b01280 -
Synthesis, structural and optical properties of tetrabenzoporphyrin complexes bearing four or eight peripheral phenyl groups
Furuyama, T.*; Okujima, T.; Muramatsu, K.; Takahashi, Y.; Mikami, A.; Fukumura, T.; Mori, S.; Nakae, T.; Takase, M.; Uno, H.; Kobayashi, N.
Eur. J. Org. Chem. 2019, 3224-3235.
DOI: 10.1002/ejoc.201900528 -
Extremely photostable electron-deficient phthalocyanines that generate high levels of singlet oxygen
Furuyama, T.*; Miyaji, Y.; Maeda, K.; Maeda, H.; Segi, M.
Chem. Eur. J. 2019, 25, 1678-1682.
DOI: 10.1002/chem.201805082
Selected as a Hot Paper
Selected as a Front Cover (Vol. 25, issue 7)
Featured in Cover Profile (Chem. Eur. J. 2019, 25, 1605.)
DOI: 10.1002/chem.201806336 -
Synthesis and peripheral substituent effects of bay-annulated indigo derivatives
Furuyama, T.*; Tamura, D.; Maeda, H.; Segi, M.
Tetrahedron Lett. 2018, 59, 2913-2916.
DOI: 10.1016/j.tetlet.2018.06.036 -
Electron photoejection from dianion of an expanded phthalocyanine
Koo, Y. H.; Yanagisawa, R.; Cha, W.-Y.; Furuyama, T.*; Kobayashi, N.; Kim, D.
J. Porphyrins Phthalocyanines 2018, 22, 437-442.
DOI: 10.1142/S1088424618500359 -
Changes of phthalocyanine visible color caused by near-IR solvatochromism
Furuyama, T.*; Uchiyama, S.; Iwamoto, T.; Maeda, H.; Segi, M.
J. Porphyrins Phthalocyanines 2018, 22, 88-94.
DOI: 10.1142/S1088424618500098 -
D-A-D type dinitriles with vapor-dependent luminescence in the solid state
Furuyama, T.*; Shinozaki, J.; Tasso, T. T.; Maeda, H.; Segi, M.; Kobayashi, N.
Tetrahedron Lett. 2017, 58, 4243-4247.
DOI: 10.1016/j.tetlet.2017.09.068
Selected as a Cover Article (Vol. 58, issue 45) -
Structural, photophysical, and magnetic circular dichroism studies of three rigidified meso-pentafluorophenyl-substituted hexaphyrin analogues
Ishida, M.; Furuyama, T.; Lim, J. M.; Lee, S.; Zhang, Z.; Ghosh, S. K.; Lynch, V. M.; Lee, C.-H.; Kobayashi, N.; Kim, D.; Sessler, J. L.
Chem. Eur. J. 2017, 23, 6682-6692.
DOI: 10.1002/chem.201700759 -
Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes
Furuyama, T.; Sugiya, Y.; Yoshida, T.; Kobayashi, N.
J. Porphyrins Phthalocyanines 2016, 20, 1075-1081
DOI: 10.1142/S1088424616500619 -
Simple primary β-amino alcohol catalyzed enantioselective Diels-Alder reaction of 3-hydroxy-2-pyridones
Takahashi, T.; Reddy, U. V. S.; Kohari, Y.; Seki, C.; Furuyama, T.; Kobayashi, N.; Okuyama, Y.; Kwon, E.; Uwai, K.; Tokiwa, M.; Takeshita, M.; Nakano H. Tetrahedron Lett. 2016, 57, 5771-5776.
DOI: 10.1016/j.tetlet.2016.11.030 -
Formation of a trithia[5]helicene in an unexpected photoreaction of a methyl-substituted bis(dithienylethenyl)thiophene through a double sequence of 6π-electrocyclization/aromatization (dehydrogenation/demethylation)
Yamamoto, A.; Matsui, Y.; Ohta, E.; Ogaki, T.; Sato, H.; Furuyama, T.; Kobayashi, N.; Mizuno, K.; Ikeda, H.
J. Photochem. Photobiol. A 2016, 331, 48-55.
DOI: 10.1016/j.jphotochem.2015.10.012 -
Double-decker bis(tetradiazepinoporphyrazinato) rare earth complexes: Crucial role of intramolecular hydrogen bonding
Tarakanova, E. N.; Trashin, S.; Simakov, A. O.; Furuyama, T.; Dzuban, A. V.; Inasaridze, L. N.; Tarakanov, P. A.; Troshin, P.; Pushkarev, V.; Kobayashi, N.; Tomilova, L. B.
Dalton Trans. 2016, 45, 12041-12052.
DOI: 10.1039/c6dt01779g -
Synthesis, optical properties, and electronic structures of tetrakis(pentafluorophenyl)tetrathiaisophlorin dioxide
Mishra, V. L.; Furuyama, T.; Kobayashi, N.; Goto, K.; Miyazaki, T.; Yang, J.-S.; Shinmyozu, T.
Chem. Eur. J. 2016, 22, 9190-9197.
DOI: 10.1002/chem.201505079 -
Preparation, optical and electrochemical properties, and molecular orbital calculations of tetraazaporphyrinato ruthenium (II) bis(4-methylpyridine) fused with one to four diphenylthiophene units
Kimura, T.; Murakami, N.; Suzuki, E.; Furuyama, T.; Nakahodo, T.; Fujihara, H.; Kobayashi, N.
J. Inorg. Biochem. 2016, 158, 35-44.
DOI: 10.1016/j.jinorgbio.2016.01.010 -
Synthesis and Photophysical Investigation of Tetraazaporphyrin Substituted with Aggregation-Induced Emission (AIE) Active Moieties
Tasso, T. T.; Furuyama, T.; Mack, J.; Nyokong, T.; Kobayashi, N.
Eur. J. Inorg. Chem. 2015, 5516-5522.
DOI: 10.1002/ejic.201500726 -
A Bottom-up Synthesis of Antiaromatic Expanded Phthalocyanines: Pentabenzotriazasmaragdyrins, i.e. Norcorroles of Superphthalocyanines
Furuyama, T.; Sato, T.; Kobayashi, N.
J. Am. Chem. Soc. 2015, 137, 13788-13791.
DOI: 10.1021/jacs.5b09853
Highlighted in “Chem-Station” -
Solution-Cast Monolayers of Cobalt Crown Ether Phthalocyanine on Highly Ordered Pyrolytic Graphite
Lu, H.; Kwak, I.; Park, J. H.; O’Neill, K.; Furuyama, T.; Kobayashi, N.; Seabaugh, A.; Kummel, A.; Fullerton-Shirey, S. K.
J. Phys. Chem. C 2015, 119, 21992-22000.
DOI: 10.1021/acs.jpcc.5b05233 -
Fluorescence Enhancement of Tetraazaporphyrins by Use of Bulky Substituent Effects
Yoshida, T.; Furuyama, T.; Asai, M.; Kobayashi, N.
Chem. Lett. 2015, 44, 1056-1058.
DOI: 10.1246/cl.150304 -
An Extremely Air-Stable 19π Porphyrinoid
Yoshida, T.; Zhou, W.; Furuyama, T.*; Leznoff, D. B.; Kobayashi, N.
J. Am. Chem. Soc. 2015, 137, 9258-9261.
DOI: 10.1021/jacs.5b05781 -
Reducing Zirconium(IV) Phthalocyanines and the Structure of a Pc –Zr Complex
Zhou, W.; Platel, R. H.; Tasso, T. T.; Furuyama, T.; Kobayashi, N.; Leznoff, D. B.
Dalton. Trans. 2015, 44, 13955-13961.
DOI: 10.1039/c5dt01778e -
Stable iso-Bacteriochlorin Mimics from Porpholactone: Effect of β-oxazolone Moiety on the Frontier π-Molecular Orbitals
Yu, Y.; Furuyama, T.; Tang, J.; Wu, Z.-Y.; Chen, J.-Z.; Kobayashi, N.; Zhang, J.-L.
Inorg. Chem. Front. 2015, 2, 671-677.
DOI: 10.1039/c5qi00054h -
Structural Changes in Non-Planar Octaaryl Substituted Phthalocyanine Phosphorus Complexes
Furuyama, T.; Harako, R.; Kobayashi, N.
J. Porphyrin Phthalocyanines 2015, 19, 500-509.
DOI: 10.1142/S1088424615500364 -
Synthesis and Spectral Properties of Nonclassical Binuclear Thienoporphyrazines
Dubinina, T. V.; Borisova, N. E.; Sedova, M. V.; Tomilova, L. B.; Furuyama, T.; Kobayashi, N.
Dyes Pigments 2015, 117, 1-6.
DOI: 10.1016/j.dyepig.2015.01.023 -
Synthesis and Optical Properties of Tetraazaporphyrin Phosphorus(V) Complexes with Electron-Rich Heteroatoms
Yoshida, T.; Furuyama, T.; Kobayashi, N.
Tetrahedron Lett. 2015, 56, 1671-1674.
DOI: 10.1016/j.tetlet.2015.02.033 -
Metallophthalocyanin-ocenes: Scandium Phthalocyanines with an η5-bound Cp Ring
Platel, R. H.; Tasso, T. T.; Zhou, W.; Furuyama, T.; Kobayashi, N.: Leznoff, D. B.
Chem. Commun. 2015, 51, 5986-5989.
DOI: 10.1039/c5cc00237k -
Dinitriles Having AIE-Active Moieties: Synthesis, E/Z Isomerization and Fluorescence Properties
Tasso, T. T.; Furuyama, T.; Kobayashi, N.
Chem. Eur. J. 2015, 21, 4817-4824.
DOI: 10.1002/chem.201406128
Highlighted as “ACS Noteworthy Chemistry” -
Optical, Electrochemical, and Magnetic Properties of Pyrrole- and Thiophene-Bridged 5,15-Diazaporphyrin Dimers
Omomo, S.; Maruyama, Y.; Furukawa, K.; Furuyama, T.; Nakano, H.; Kobayashi, N.; Matano, Y.
Chem. Eur. J. 2015, 21, 2003-2010.
DOI: 10.1002/chem.201405482 -
Control of Absorption Properties of Tetraazaporphyrin Group 15 Complexes by Modification of their Axial Ligands
Furuyama, T.; Asai, M.; Kobayashi, N.
Chem. Commun. 2014, 50, 15101-15104.
DOI: 10.1039/c4cc07408d -
Enantioselective Diels-Alder Reaction of 1,2-Dihydropyridines with Aldehydes using β-Amino Alcohol Organocatalyst
Kohari, Y.; Okuyama, Y.; Kwon, E.; Furuyama, T.; Kobayashi, N.; Otuki, T.; Kumagai, J.; Seki, C.; Uwai, K.; Dai, G.; Iwasa, T.; Nakano, H.
J. Org. Chem. 2014, 79, 9500-9511.
DOI: 10.1021/jo501433c -
Synthesis of New Chlorin e Trimethyl and Protoporphyrin IX Dimethyl Ester Derivatives and Their Photophysical and Electrochemical Characterizations
Menezes, J. C. J. M. D. S.; Faustino, M. A. F.; de Oliveira, K. T.; Uliana, M. P.; Ferreira, V. F.; Hackbarth, S.; Röder, B.; Tasso, T. T.; Furuyama, T.; Kobayashi, N.; Silva, A. M. S.; Neves, M. G. P. M. S.; Cavaleiro, J. A. S.
Chem. Eur. J. 2014, 20, 13644-13655.
DOI: 10.1002/chem.201403214 -
Synthesis of Tetrabenzotriazacorrole-Subphthalocyanine µ-Oxo Triad
Furuyama, T.; Sugiya, Y.; Kobayashi, N.
Macroheterocycles 2014, 7, 139-144.
DOI: 10.6060/mhc140488k -
Synthesis and Spectroscopic Properties of Chiral Binaphthyl-Linked Subphthalocyanines
Zhao, L.; Wang, K.; Furuyama, T.; Jiang, J.; Kobayashi, N.
Chem. Commun. 2014, 50, 7663-7665.
DOI: 10.1039/c4cc03426k -
High Diastereoselection of Dissymmetric Capsule by Chiral Guest Complexation
Tsunoda, Y.; Fukuta, K.; Imamura, T.; Sekiya, R.; Furuyama, T.; Kobayashi, N.; Haino, T.
Angew. Chem. Int. Ed. 2014, 53, 7243-7247.
DOI: 10.1002/anie.201403721 -
Synthesis and Characterization of Aza-Bridged Thiophene-Pyrrole Dyads and Their Isomers
Furuyama, T.; Noguchi, D.; Suzuki, Y.; Kobayashi, N.
Can. J. Chem. 2014, 92, 765-770.
DOI: 10.1139/cjc-2014-0039 -
Phosphorus(V) Tetraazaporphyrins: Porphyrinoids Showing an Exceptionally Strong CT Band between the Soret and Q Bands
Furuyama, T.; Yoshida, T.; Hashizume, D.; Kobayashi, N.
Chem. Sci. 2014, 5, 2466-2474.
DOI: 10.1039/c4sc00569d -
Synthesis of Tetrabenzotriazacorrole µ-Oxo Dimer and Investigation of Its Stacking Effect
Furuyama, T.; Sugiya, Y.; Kobayashi, N.
Chem. Commun. 2014, 50, 4312-4314.
DOI: 10.1039/c4cc01115e -
An Exemplary Relationship between the Extent of Cofacial Aggregation and Fluorescence Quantum Yield as Exhibited by Quaternized Amphiphilic Phthalocyanines
Tasso, T. T.; Yamasaki, Y.; Furuyama, T.; Kobayashi, N.
Dalton Trans. 2014, 43, 5886-5892.
DOI: 10.1039/c4dt00195h -
Design, Synthesis and Properties of Phthalocyanine Complexes with Main-Group Elements Showing Main Absorption and Fluorescence beyond 1000 nm
Furuyama, T.; Satoh, K.; Kushiya, T.; Kobayashi, N.
J. Am. Chem. Soc. 2014, 136, 765-776.
DOI: 10.1021/ja411016f -
Absorption and Electrochemical Properties of Cobalt and Iron Phthalocyanines and Their Quaternized Derivatives: Aggregation Equilibrium and Oxygen Reduction Electrocatalysis
Tasso, T. T.; Furuyama, T.; Kobayashi, N.
Inorg. Chem. 2013, 52, 9206-9215.
DOI: 10.1021/ic4002048 -
Superazaporphyrins: Meso-Pentaazapentaphyrins and One of Their Low-Symmetry Derivatives
Furuyama, T.; Ogura, Y.; Yoza, K.; Kobayashi, N.
Angew. Chem. Int. Ed. 2012, 51, 11110-11114.
DOI: 10.1002/anie.201203191 -
A Zinc Gable Phthalocyanine and a Derived Planar Bis-phthalocyanine Containing a Shared Anthracene Unit
Asano, Y.; Sato, J.; Furuyama, T.; Kobayashi, N.
Chem. Commun. 2012, 48, 4365-4367.
DOI: 10.1039/C2CC31264F -
Aluminepin: Aluminum Analogues of Borepin and Gallepin
Yoshida, K.; Furuyama, T.; Wang, C.; Muranaka, A.; Hashizume, D.; Yasuike, S.; Uchiyama, M.
J. Org. Chem. 2012, 77, 729-732.
DOI: 10.1021/jo201992q -
Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center
Jiang, X.-D.; Zhang, J.; Furuyama, T.; Zhao, W.
Org. Lett. 2012, 14, 248-251.
DOI: 10.1021/ol2030229 -
Rationally Designed Phthalocyanines Having Their Main Absorption Band beyond 1000 nm
Kobayashi, N.; Furuyama, T.; Satoh, K.
J. Am. Chem. Soc. 2011, 133, 19642-19645.
DOI: 10.1021/ja208481q -
Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches
Takaishi, K.; Kawamoto, M.; Tsubaki, K.; Furuyama, T.; Muranaka, A.; Uchiyama, M.
Chem. Eur. J. 2011, 17, 1778-1782.
DOI: 10.1002/chem.201003087 -
Calix[3]amide-based Anion Receptors: High Affinity for Fluoride Ion and Twisted Binding Model
Katagiri, K.; Furuyama, T.; Masu, H.; Kato, T.; Matsumura, M.; Uchiyama, M.; Tanatani, A.; Tominaga, M.; Kagechika, H.; Yamaguchi, K.; Azumaya, I.
Supramolecular Chemistry 2011, 23, 125-130.
DOI: 10.1080/10610278.2010.514909 -
1,4-Addition of Bis(iodozincio)methane to ɑ,β-Unsaturated Ketones: Chemical and Theoretical/Computational Studies
Sada, M.; Furuyama, T.; Komagawa, S.; Uchiyama, M.; Matsubara, S.
Chem. Eur. J. 2010, 16, 10474-10481.
DOI: 10.1002/chem.201000738 -
Reaction Mechanism for the LiCl-Mediated Directed Zinc Insertion: A Computational and Experimental Study
Liu, C.-Y.; Wang, X.; Furuyama, T.; Yasuike, S.; Muranaka, A.; Morokuma, K.; Uchiyama, M.
Chem. Eur. J. 2010, 16, 1780-1784.
DOI: 10.1002/chem.200902957 -
Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB Monomer Making Use of Changed Substituent Effects
Ohta, Y.; Fujii, S.; Yokoyama, A.; Furuyama, T.; Uchiyama, M.; Yokozawa, T.
Angew. Chem. Int. Ed. 2009, 48, 5942-5945.
DOI: 10.1002/anie.200901714 -
Application of the Perimeter Model to the Assignment of the Electronic Absorption Spectra of Gold(III) Hexaphyrins with [4n+2] and [4n] π-Electron Systems
Muranaka, A.; Matsushita, O.; Yoshida, K.; Mori, S.; Suzuki, M.; Furuyama, T.; Uchiyama, M.; Osuka, A.; Kobayashi, N.
Chem. Eur. J. 2009, 15, 3744-3751.
DOI: 10.1002/chem.200801742 -
Development of Highly Chemoselective Bulky Zincate Complex, tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis
Furuyama, T.; Yonehara, M.; Arimoto, S.; Kobayashi, M.; Matsumoto, Y.; Uchiyama, M.
Chem. Eur. J. 2008, 14, 10348-10356.
DOI: 10.1002/chem.200800536 -
Structural Development of Benzhydrol-Type 1’-Acetoxychavicol Acetate (ACA) Analogs as Human Leukemia Cell-Browth Inhibitors Based on Quantitative Structure-Activity Relationship (QSAR) Analysis
Misawa, T.; Aoyama, H.; Furuyama, T.; Dodo, K.; Sagawa, M.; Miyachi, H.; Kizaki, M.; Hashimoto, Y.
Chem. Pharm. Bull. 2008, 56, 1490-1495.
DOI: 10.1248/cpb.56.1490 -
Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP-Zn-ate): New Approaches to Multisubstituted Benzenes
Uchiyama, M.; Kobayashi, Y.; Furuyama, T.; Nakamura, S.; Kajihara, Y.; Miyoshi, T.; Sakamoto, T.; Kondo, Y.; Morokuma, K.
J. Am. Chem. Soc. 2008, 130, 472-480.
DOI: 10.1021/ja071268u -
Reaction Pathway of Conjugate Addition of Lithium Organozincates to s-trans-Enones
Uchiyama, M.; Nakamura, S.; Furuyama, T.; Nakamura, E.; Morokuma, K.
J. Am. Chem. Soc. 2007, 129, 13360-13361.
DOI: 10.1021/ja070123k -
Toward a Protecting-Group-Free Halogen-Metal Exchange Reaction: Practical, Chemoselective Metalation of Functionalized Aromatic Halides Using Dianion-Type Zincate, tBu4ZnLi2
Uchiyama, M.; Furuyama, T.; Kobayashi, M.; Matsumoto, Y.; Tanaka, K.
J. Am. Chem. Soc. 2006, 128, 8404-8405.
DOI: 10.1021/ja058246x -
Structure and Reaction Pathway of TMP-Zincate: Amido Base or Alkyl Base?
Uchiyama, M.; Matsumoto, Y.; Nobuto, D.; Furuyama, T.; Yamaguchi, K.; Morokuma, K.
J. Am. Chem. Soc. 2006, 128, 8748-8750.
DOI: 10.1021/ja060489h -
Inductive Effect-Assisted Chain-Growth Polycondensation. Synthetic Development from para- to meta-Substituted Aromatic Polyamides with Low Polydispersities
Sugi, R.; Yokoyama, A.; Furuyama, T.; Uchiyama, M.; Yokozawa, T.
J. Am. Chem. Soc. 2005, 127, 10172-10173.
DOI: 10.1021/ja052566z
1,5
6
2
総説・解説記事
-
近赤外光反応制御を目指した有機色素の合成化学(総合論文)
古山渓行
有機合成化学協会誌、2024, 82, 989-1000.
DOI: 10.1142/S1088424622300014 -
Development of controlled reactions using an element-based design of azaporphyrinoid materials
Furuyama, T.
J. Porphyrins Phthalocyanines 2022, 26, 790-806.
DOI: 10.1142/S1088424622300014
(Award Account for SPP/JPP Young Investigator Award) -
近赤外光活用を目指した有機機能性色素の合成技術(解説記事)
古山渓行
ファインケミカル、2021, 50 (9), 12-17, -
近赤外光と強く相互作用する有機金属錯体の開発(解説記事)
古山渓行
光化学、2021, 52, 25-28. -
親水性ケイ素フタロシアニンの近赤外光線力学療法への応用(解説記事)
石井孝知、古山渓行
マテリアルステージ、2021 (1), 80-84. -
近赤外光を活用できる有機金属錯体の合成技術(解説記事)
古山渓行
オプトロニクス、2020, 458, 134-139. -
典型元素を活用するフタロシアニン光材料の合成(解説記事)
古山渓行
化学工業、2019, 70, 169-174. -
機能性π共役化合物の設計・合成と近赤外光利活用への挑戦
古山 渓行
薬学雑誌、2018, 138, 731-742.
DOI: 10.1248/yakushi.17-00233.
(平成29年度日本薬学会奨励賞受賞記念総説) -
Azaporphyrin Phosphorus(V) Complexes: Synthesis, Structure, and Modification of Optical Properties (Perspective)
Furuyama, T.; Kobayashi, N.
Phys. Chem. Chem. Phys. 2017, 19, 15596-15612.
DOI: 10.1039/c7cp02155k.
Featured in “2017 PCCP HOT Articles” -
高原子価リンを活用するアザポルフィリン誘導体のデザイン・合成・機能開発(総合論文)
古山 渓行、小林 長夫
有機合成化学協会誌、2015, 73, 833-843.
DOI: 10.5059/yukigoseikyokaishi.73.833. -
高原子価リンを活用したアザポルフィリン類の光特性制御(解説記事)
古山 渓行
化学と工業、2015, 68, 644-645. -
近赤外光の有効利用に向けて—合理的にデザインされたフタロシアニン誘導体(解説記事)
小林 長夫、古山 渓行
化学、2013, 68, 66-67. -
歪んだ3員環を自在に操る新しい有機合成(解説記事)
古山 渓行
ファルマシア、2009, 45, 1250. -
酸化過程を経由する新しいアミド結合形成反応の新展開(解説記事)
古山 渓行
有機合成化学協会誌、2008, 66, 1005-1006.
特許
-
フタロシアニン系化合物、膜及びフタロシアニン系化合物の製造方法
古山 渓行、中谷 友哉、前田 和哉、前多 肇、千木 昌人
特開2023-066025 -
金属錯体及び金属錯体の製造方法
古山 渓行、島崎 史佳、前多 肇、千木 昌人
特許第7064764号 -
組成物、近赤外光電変換素子および撮像素子
飯島 浩章、平出 雅哉、中田 学、古山 渓行
特許第6767695号 -
赤外吸収フタロシアニン
小林 長夫、古山 渓行、佐藤 皓、辻 良太郎、太和田 善久
特開 2013-103911 -
新規な化合物、その合成中間体及びそれらの製造方法
内山 真伸、古山 渓行、吉田 健吾
特開2010-202616
依頼・招待講演
-
Functional Integration of Near-Infrared-Light-Absorbing Ball-Shaped Metal Complexes(Invited Oral)
13th International Conference on Porphyrin and Phthalocyanines (ICPP-13)(Buffalo, USA)
2024年6月24日 -
近赤外光を活用できる有機材料の合成と機能開発(依頼講演)
第1回金沢大学ナノマテリアル研究所シンポジウム(石川県金沢市)
2023年12月7日 -
光反応制御を目指した近赤外色素合成化学(招待講演)
九州大学大学院総合理工学研究院・理学研究院特別講演会(福岡県福岡市)
2023年10月30, 31日 -
近赤外NIR-II領域を活用できる新材料(依頼講演)
JST戦略的創造研究推進事業① 〜さきがけ研究領域「反応制御」〜 新技術説明会(オンライン)
2023年10月20日
発表詳細・資料
講演動画 -
近赤外光反応制御が拓く有機合成化学(招待講演)
神戸大学大学院工学系研究科講演会(兵庫県神戸市)
2023年9月15日 -
Design of Controlled Near-infrared Light-responsive Photocatalysts(Invited Oral)
2023 Taiwan-Japan Symposium on Reaction Control (TJSReC)(Hsinchu, Taiwan)
2023年7月29日 -
Organic Reactions Using Near-infrared Light Mediated Controlled Photocatalysts(Invited Oral)
18th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23)(Shiga, Japan)
2023年6月10日 -
近赤外光反応制御を指向した有機材料の開発(招待講演)
新潟大学コアステーション「ユビキタスグリーンケミカルエネルギー連携教育研究センター」第13回研究シンポジウム(新潟県新潟市)
2023年3月14日 -
Development of Controlled Reactions Using Phthalocyanine-based Materials(Award Lecture)
12th International Conference on Porphyrin and Phthalocyanines (ICPP-12)(Madrid, Spain)
2022年7月13日 -
Photocatalysis Mediated by Far-red Light(Keynote Lecture)
6th International Conference on Catalysis and Chemical Engineering (CCE-2022)(Online)
2022年2月23日 -
光触媒の能動的制御による近赤外光合成プロセスの開発(招待講演)
さきがけ「電子やイオン等の能動的制御と反応」領域 オンライン公開シンポジウム(1期生研究成果発表会) (オンライン)
2022年1月8日 -
機能性フタロシアニンの開発(招待講演)
企業向け社内講演会
2021年12月8日 -
有機近赤外色素の合成技術・創成・機能開発(招待講演)
第6回「生体適合化学の進歩」インタラクティブフォーラム(オンライン)
2021年9月22日
講演動画 -
Axial ligand effects on sulfur-substituted silicon(IV) phthalocyanines(Invited Oral)
11th International Conference on Porphyrin and Phthalocyanines (ICPP-11)(Online)
2021年6月29日 -
精密有機合成技術に基づく近赤外色素材料の開発と応用(招待講演)
金沢大学先端科学・イノベーション推進機構協力会 第16回金沢大学研究室見学会(石川県金沢市)
2021年2月19日 -
近赤外光を活用できる機能性色素の精密有機合成技術(招待講演)
岡山大学次世代研究育成グループ「精密有機合成に基づく高機能性有機色素の開発」講演会(岡山県岡山市)
2020年2月7日 -
近赤外域に強い吸収を持ち、光波長特性を制御可能な有機色素材料の開発(招待講演)
企業向け社内講演会
2020年1月30日 -
近赤外光を活用できる有機ルテニウム錯体の合成技術(依頼講演)
2019 金沢大学新技術説明会(東京都千代田区)
2019年8月22日
発表詳細・資料 -
電気・光特性を自在に活用できる有機材料の開発(招待講演)
2019年度電気化学会北陸支部春季(石川)大会(石川県金沢市)
2019年6月14日 -
Synthesis of ball-shaped metal complexes with a main absorption band in the near-IR region(Invited Oral)
7th Geogian Bay International Conference on Bioinorganic Chemistry (CanBIC-7)(Parry Sound, Canada)
2019年5月22日 -
分子の「かたち」から「しくみ」を見通す有機化学(企画講演)
国際科学技術財団 第320回やさしい科学技術セミナー(石川県金沢市)
2018年11月18日
講演動画 -
元素の特性を利用した有機近赤外光材料の開発(招待講演)
第3回有機若手ワークショップ(京都府京都市)
2018年11月8日 -
アザポルフィリンを活用する近赤外光材料の開発(依頼講演)
第38回光化学若手の会(福岡県福岡市)
2017年6月17日 -
機能性π共役化合物の設計・合成と近赤外光利活用への挑戦(日本薬学会奨励賞受賞講演)
日本薬学会第137年会(宮城県仙台市)
2017年3月25日 -
元素特性を活用したアザポルフィリン光材料の開発(依頼講演)
第5回化学フロンティア研究会(高知県高知市)
2016年7月31日 -
An air-stable 19π azaporphyrinoid radical(Invited Oral)
9th International Conference on Porphyrin and Phthalocyanines (ICPP-9)(Nanjing, China)
2016年7月4日 -
元素の特性を活用したアザポルフィリン類の合成・光物性制御(若い世代の特別講演)
日本化学会第95春季年会(千葉県船橋市)
2015年3月26日 -
フタロシアニン典型元素錯体の開発と性質(依頼講演)
第30回無機・分析化学コロキウム(宮城県大崎市)
2013年6月1日